How many gallons of boiling water (212°) must one add to get a 5000 gallon pool with 75°F water up (+10°) to 85°F 
It assumes that the new volume will be 5,393.7 gallons.
Is this something that you're planning to do?
Also, note that the answer is different depending on the starting temperature. Going up 10 degrees takes more boiling water as the starting temperature increases.
For example, starting at absolute zero (not possible, but just for example and not including ice). It would take 75.5 gallons of boiling water to increase the temperature 10 degrees.
To go from 201 f to 211 f , it would take 50,000 gallons.
It would not be possible to go from 202 f to 212 f by adding water at 212 f (it would take an infinite amount).
If you used steam at 212 degrees Fahrenheit, then it would only take about 52 lbs of steam, which wound condense into about 6 gallons of water.
It assumes that the new volume will be 5,393.7 gallons.
Is this something that you're planning to do?
Also, note that the answer is different depending on the starting temperature. Going up 10 degrees takes more boiling water as the starting temperature increases.
For example, starting at absolute zero (not possible, but just for example and not including ice). It would take 75.5 gallons of boiling water to increase the temperature 10 degrees.
To go from 201 f to 211 f , it would take 50,000 gallons.
This was an idea that crossed my mind when i was in a pinch, not be the standard method id use on a day to day basis.
Might have been watching too much James Bond, but what about a parabolic trough mirrors on solar tracking gimbals...
They use those in solar power plants. Sometimes they use molten salt to transfer the energy.