This looks a lot like copper stains.
Copper usually starts out as turquoise and then begins to turn black.
You probably also have black algae as well, which makes it harder to diagnose the problems individually.
Most likely, the copper was added as a treatment for the black algae.
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Huh,
I never contemplated it could be both. Years ago dad dumped copper in, in an attempt to control early algae I assume.
Would those stains dissipate in a similar way to mine from high FC and backbreaking scrubbing?