Well, here's some science from the WHO (World Health Organization) on it's use as a potable water purification method.
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Here is some less tedious reading.
description of water copper-silver ionization as a disinfectant
www.lenntech.com
Here is what Wikipedia has on the subject.
en.m.wikipedia.org
So, now that we have addressed the science, I will say that I swear by mineral purifiers, use them in my own spa, and recommend them to my customers. The cartridge used by D1 is a bit higher priced than other available products (spa frog, nature2) but lasts longer. Check out those other products for a comparison.
Sorry, but that does not really address the science.
Those are nice articles that explain some of the science behind what minerals can
potentially do, but they do not address the fundamental question of whether or not the presence of minerals in recreational water (pools or spas) are
effective enough to act as a proper sanitizer. The short answer is, they are not effective from a disease transmission standpoint. And, since we are talking about a hot tub here, person-to-person disease transmission is absolutely the most important aspect to discuss.
The EPA only allows mineral sanitizer in a hot tub when two conditions are met - the water temperature is above 100F AND there is a residual oxidizer present (typically MPS). The reasoning behind those conditions is due to the pathogen inactivation time. When those conditions are met, certain pathogens, such as legionella, have adequate inactivation times. When those conditions are not met, pathogens can survive and grow. Here are some links to threads written by
@chem geek that details much of the actual science related to alternative sanitizers and their pathogen inactivation times. [EDIT]
Unfortunately there used to be a single post on TFP written by @chem geek that had a very nice chart with all of the journal references related to mineral ions and their kill times with respect to various bacteria and viruses, but that link got nuked when the forum switched over to the new software.[END-EDIT] If I get a copy of that page/post, I will add it back here. For now, there are posts from Richard on other forums that give insights into why minerals are not advised -
only in New Zealand, can people get away with selling this s**t, http://simplesilver.co.nz and the number thta have jumped on this bandwagon is unbelievable :hammer: we have a national swimming pool water quality standard - however lax authorites mean you can package any form of...
www.troublefreepool.com
I believe I finally found a scientific source that would explain the effective use of MPS in hot tubs for disinfection supporting the Nature2 claims and results regarding their "low chlorine recipe". The following is the information and source: At 77ºF Potassium Monopersulfate provided only 16.8%...
www.poolspaforum.com
The short answer is this, in a private residential settings, you might be able to get away with clear looking water using a mineral sanitizer in a hot tub and it could likely be safe enough for you and your family since you all share the same "bugs" day-in and day-out. But, given the fluctuations in temperature and sanitizer levels, it is more than likely a residential hot tub will be home to lots of disease-causing pathogens and, if friends come over, you are exposing them to whatever you have and they are exposing you to whatever they have. Chlorine, when used properly, is the single most effective sanitizer you can use, hands-down. Everything else is an unnecessary and expensive complications. When you couple good hot tub care, with proper water maintenance (plumbing purges) and the proper use of chlorine, a hot tub can be as trouble free as a pool.