Best chemistry startup sequence after winter season

tors10

Member
Oct 19, 2023
10
Germany
Pool Size
30000
Surface
Fiberglass
Chlorine
Liquid Chlorine
Hello Folks,

i've read all of the Pool School articles, especially:
but it does not give you any insights about the best sequence (e.g. increasing TA also increases PH etc).

Setup:
Location: south of Germany
Fiberglass Pool, 30 cubic meters of water, sand filter, automatic dosing of liquid chlorine and acid (for lowering PH).
Starting up with fresh tap water (PH 8.1, Alkalinity 5, Calcium 50, CYA 0, Chlorine 0).

TFP recomended levels are PH 7.7, Alkalinity 70, Calcium 450, CYA 45, Chlorine 6-7.

But how to get there? What is the best sequence?

Thanks in advance,
Torsten
 
How are you testing?

pH of 8.1 and TA of 5 make no sense.

Where did you get those TFP recommendations from? TFP does not recommend a CYA of 45. Fiberglass pools do not need calcium unless you have a gas heater.

TFP recommends ranges not specific values. Anywhere in a range is fine.


 
sorry, TA was wrong. TA is 64 ppm. These values are from the official testing authority:
https://vg-maikammer.de/wp-content/uploads/2024/02/Trinkwasseranalyse-2023.pdf in the second column, "Carbonathärte" in dH (1 dH is 17,9 ppm or mg/l).

I have chosen the mean value of the ideal ranges... PH 7.7, Alkalinity 70, Calcium 450, CYA 45, Chlorine 6-7.
I do see Calcium recommendation here for Fiberglass pools...

1711464946867.png
 
You need to adapt TFP Methods to your testing methods which may be different then what TFP recommended levels are based on. And you need to adjust your target values to your pool equipment and environment.

Choosing the mean of the recommendation chart is not the way to do it.

Do you know if the reported TA is the raw TA tested value or an adjusted TA as many pool store tests do? TA recommendations are based on the raw TA values and an adjusted TA makes the TA look lower. Read TA - Further Reading

Some Pool Tests test total hardness and call it Calcium Hardness. Are you sure your test is only reporting calcium hardness.

It is important to understand what to us is a non-standard test is accurately reporting before you try to apply TFP Guidelines which are specifically based on testing with Taylor test kits.

The chart you posted is a generic chart that has the most conservative values to apply globally regardless of pool equipment. If you do not have a gas heater then a modern fiberglass pool does not need calcium unless the manufacturer recommends it.
 
You sound like a pretty smart guy: buy the TFT-100 test kit and follow the method for a trouble-free pool.
Note he is in Germany and so getting one of the TFP recommended test kits is not easy in the EU.
 
I'm using this photometer ( easy to get for me because created by a german company ;-) )


The TA test is done with these tablets:
Hexanedioic acid: https://msds.water-id.com/storage/msds/Alkalinity-M Photometer - TBSPTA - US - en.PDF

I think Calcium test is done with these liquids:
Acetic acid: https://msds.water-id.com/storage/m...- POL20CH1_from_exp._d._09.2024 - GB - en.pdf
Ethanedioic acid: https://msds.water-id.com/storage/msds/Calcium Hardness No.2 - POL20CH2 - GB - en.pdf
 
Environment:
Fiberglass pool, construction date 2001
Heating: Air-Water Heat Pump
Filtering: Sandfilter
automatic dosing of liquid chlorine and muriatic acid (for lowering PH).
 
The limits on the range of chlorine testing with the Poollab is an issue with using it with TFP methods…

 
Environment:
Fiberglass pool, construction date 2001
Heating: Air-Water Heat Pump
Filtering: Sandfilter
automatic dosing of liquid chlorine and muriatic acid (for lowering PH).
You need to determine what the manufacturer of your 23 year old pool requires for calcium. That is the only reason to maintain a specific level with your equipment list.

Please put your equipment list on your signature.

 

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sorry for the typo, construction date is 2021.

OK, understood the limits of FC testing with Poollab, I will try to get a FAS/DPD Test somewhere.

But, back to my original question:
Where should I start now to examine the best values for my environment?
e.g. start with Alkalinity, raise to 90, look at PH, see if it is stable or not...
 
Forget about your alkalinity right now.

Get your CYA around 40 and keep your FC in range for your CYA.
FC/CYA Levels

Keep your pH in the 7’s.

Calcium does not matter for you.

Use PoolMath to calculate your CSI and keep it negative to prevent any scaling.

Done!
 
sorry, TA was wrong. TA is 64 ppm. These values are from the official testing authority:

Carbonathärte is calcium hardness (CH), as opposed to Gesamthärte further up the list which is Total Hardness (also includes Magnesium Hardness).

Alkalinity doesn't seem to be in the list.

But, back to my original question:
Where should I start now to examine the best values for my environment?
e.g. start with Alkalinity, raise to 90, look at PH, see if it is stable or not...

Keep in mind that higher TA doesn't mean more stable pH. Yes TA is z measure for the buffering capability of the water. But the main contributor to TA is Carbonate Alkalinity (Alkalinity Increaser is Bicarbonate of Soda). The higher the TA, the more oversaturated the water is with dissolved Carbon Dioxide. This wants to gas out, like in an opened soda water bottle, raising pH in the process.

The higher TA is, the faster pH rises. This is only desirable when using Trichlor for chlorination which is acidic, driving pH and TA down. When using liquid chlorine or an SWG (as we recommend to avoid CYA accumulation), which is pH-neutral over the complete chlorination cycle), then there is nothing to counteract the constant pH-rise from CO2 outgassing. In this case a TA around 60-70 usually works better.

Low CSI is not a concern for a FG pool, unless you have a waterline tile with mortar, I would maintain TA just above 50, something like 60 or 70.

pH should then stabilise (or at least rise only slowly) in the higher sevens range. Which is fine if CYA is used, which flattens the pH-dependency of the HOCl concentration (which is the relevant sanitizing chlorine species).

As said above, first concern is CYA/FC.
 
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