Did Polyquat jack up my pH... or is it interfering with R-0004/T-9056??

Sampo

Gold Supporter
Aug 19, 2022
68
Southeast PA
Pool Size
34000
Surface
Plaster
Chlorine
Salt Water Generator
SWG Type
CircuPool RJ-60 Plus
Hi TFP friends! I need some help.

For background, I'm in the process of closing for the first time by myself 🥳. My chemistry had been balanced and very predictable for months (thanks to TFP). After doing a "soft close" on Saturday (solid cover on, but pump still running), I'd passed my OCLT, had FC perfect at 1/2 SLAM level, and was just waiting a few more days to get my temps solidly below 60F before winterizing. But then I added Polyquat... and my pH results went crazy! Here are more details of what happened:

  • Prior full panel (10/12/24 13:52 pm): FC=12.0, CC=0.5, pH=7.5, TA=70, CH=400, CYA=60, NaCl=3,200, Temp=60F, CSI=-0.48.
  • Last reliable pH (10/13/24 10:15 am): pH=7.6. (also passed OCLT)
  • Added 40 oz Polyquat 60% (10/13/24 10:29 am). Nothing else added. Cover had been on. SWG off for a while.
  • Next pH test (10/13/24 17:34 pm): pH= "iridescent magenta" -- off the scale (best guess = 8.4?). Whoa! 😲 Test repeated: same result.
  • Added ~0.25 gal 31.45% HCl (10/13/24 21:11 pm).

At this point, I started searching through TFP forums. I found this discussion which suggested that the result might be an artifact -- a false reading from the drop test. In fact, I'd seen that same "iridescent magenta" color in my comparator once before: last year after my PB closed my pool (they also used Polyquat, although I previously thought that they really did shoot up my pH by using a weird borate-containing winter float :cautious:).

Since I wanted an independent check of the pH reading with any other methodology than my Taylor test, I just went to Leslie's for the first time in about a year (I know, I know -- I'm sorry! 🫣). Their results: pH=8.1 (ok, maybe...), and TA=5 (false for sure! My TA has been rock-solid stable at 70).
Funny aside: their tech had never heard of Polyquat (lol)... but he did predictably tell me that my phosphates (1325 ppb) were "algae food!". But I digress.

After coming home, I've rerun my Taylor test several times (I'm using R-0004/T-9056). The end result is always that same "iridescent magenta" color, suggesting that my pH is 8.0++ (picture below). But after several runs, I've noticed something interesting: the sample first flashes orange (pH=7.4-7.6 range) for the briefest of moments... before quickly turning magenta -- only for about a second as I'm shaking the comparator.

Based on the prior TFP discussion I've linked above, my current best guess is that the orange flash is real and that the magenta color is false: that my pH is really ~7.5 (implying a CSI=-0.48)... rather than being absurdly high at around 8.2+ (implying a CSI=+0.39). That would fit based on where my pH had been before the Polyquat and my panic-addition of the muriatic acid above -- based on what I intuitively know about pH levels in my pool.

But is there a way to know for sure? Or does it even matter? The pH is sure to rise in the winter, so I'd love to start it off right.

Thanks for your thoughts, and CYA later!
Sampo

Polyquat did this.JPG
 
Polyquat and linear quat algaecides are organic compounds that are known to cause interference's with certain color indicating reagents like pH indicators (as you have seen and others have reported the purple results). Adjust the pH before adding Polyquat 60 and there is no reason to test pH after adding it.
 
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I would not worry about it.

I get my pH and FC right for close and then add Polyquat. Once the Polyquat is added I don't check the chemistry during the closing.
 
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Interesting. It just feels so antithetical to everything that I've learned about TFP methods: we check a starting level using a reliable test, then add chemicals with intention, and finally recheck levels to be sure that the addition had the expected effect. That is, I'm so used to checking levels before/after chemicals -- particularly with something that I haven't used before (Polyquat) that verifying the pH afterwards was just habit. But your approach makes sense in this one context, given the interference you mention.
 
Also since there is talk about chlorine oxidizing the polyquat chains into shorter strands, I was academically curious to see if the FC dropped after the Polyquat addition (it didn't -- although the CC became slightly pinker, but still <=0.5).
 
Also since there is talk about chlorine oxidizing the polyquat chains into shorter strands, I was academically curious to see if the FC dropped after the Polyquat addition (it didn't -- although the CC became slightly pinker, but still <=0.5).

That does not happen overnight. The Polyquat will interact with the chlorine over the long term.
 
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